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91.
The effect of Fe-doping on the structural, morphological and optical properties of ZnO nanoparticles synthesized by simple solution combustion process are reported. The powder XRD pattern indicates that the Fe-doped ZnO samples exhibit primary and secondary phases. The primary phase indicates the hexagonal wurtzite structure with the average crystalline size of around 25–50 nm and the secondary phase is associated with the face centered cubic structure of magnetite iron oxide. The elemental composition of pure and Fe-doped samples are evaluvated by EDX. The results of FE-SEM and HR-TEM cleary show that particles morphology have changed with respect to the incorporation of doping agent and particles are in aggregating nature. The vibrational properties of the synthesized ZnO nanoparticles are investigated by Raman scattering technique and it exhibits that the influence of Fe-doping significantly modify the lattice vibrational characteristics in ZnO sites. The optical properties of the Fe-doped ZnO nanoparticles are carried out by UV–vis absorption and PL spectra. The results of PL spectra show the near-band edge related emission as well as strong blue emissions in the Fe-doped ZnO nanoparticles. 相似文献
92.
燃烧系统的诸多模拟依托于流体建模, 离散Boltzmann方法(discrete Boltzmann method, DBM) 是近年来发展起来的一种新的流体介观建模方法. 本文简要评述DBM发展的两个方向——Navier-Stokes等偏微分方程的数值逼近解法和复杂系统的微介观动理学建模. 主要介绍在燃烧系统模拟方面DBM已有的工作、新近的思路、与传统流体建模的异同以及近期的研究成果. 本文重点传递的信息为: 作为复杂系统微介观动理学建模出现的DBM在模拟过程中同时给出“流动”及其相伴随的、关系最密切的那部分“热动”非平衡效应; 它为燃烧等复杂系统中各类非平衡行为的描述、非平衡信息的提取、非平衡程度的度量提供了一种简洁、有效的方法; 它所提供的热动非平衡测量量有两类: 一类是直接比较分布函数和平衡态分布函数的动理学矩关系得到的, 一类是来自于Chapman-Enskog多尺度分析给出的热传导和黏性项. 基于第二类DBM, 可以实现(燃烧等)一大类复杂流体系统的多尺度物理建模. 相似文献
93.
Electron Temperatures and Electron Densities in Microwave Helium Discharges with Pressures Higher than 0.1 MPa 下载免费PDF全文
We adopted laser Thomson scattering for measuring the electron density and the electron temperature of microwave plasmas produced in helium at the pressures higher than the atmospheric pressure. The electron density decreased while we observed the increase in the electron temperature with the pressure. These are reasonable results by considering the decrease in the reduced electric field, the dominant loss of electrons via three‐body recombination with helium as the third body, and the production of electrons with medium energy via heavy particle collisions at the high gas pressure. The temporal variation of the electron temperature had the rise and the fall time constants of approximately 10 ns. The rapid heating and cooling of the electron temperature are due to the fast energy transfer from electrons to helium because of the high collision frequency in the high‐pressure discharge. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
94.
建立了描述可燃粉全-氧气混合物爆轰波的一维两相反应流模型,用MacCormack有限差分格式求解了控制方程,成功地模拟了玉米粉-氧气混合物在氢-氧爆轰驱动下爆轰波的传播过程,其数值结果在接近稳态爆轰区时与实验规律有良好的一致性。 相似文献
95.
96.
采用黏性激波层基本方程组对有无泰氟龙烧蚀两种情况下的钝锥体化学非平衡绕流作了数值求解,以研究泰氟龙烧蚀对流场电子密度的影响规律.算例结果表明:泰氟龙烧蚀确有降低流场电子密度的效应.平衡催化壁工况下这种效应的强度,显著大于非催化壁工况下的强度;远下游截面处的这种效应的强度,显著大于驻点区的强度.此外,通过计算结果分析,对形成上述影响规律的原因作了初步讨论. 相似文献
97.
Effective stress law of all kinds of coal samples, including steam coal, fat coal, corking coal, thin coal and anthracite, under pore pressure of gas, is experimentally studied using a newly developed test machine. These samples are taken from Coal Mines in Wuda, Hebi, Yanzhou, Yangquan, Qingshui, and Gujiao in China. The experiment results show that, under pore pressure of gas, the tested coal samples comply with Biots effective stress law,
where the Biots coefficient is not a constant, and is bilinear function of volumetric stress () and pore pressure (p), that is,
We define four areas according to the numerical feature of , that is, functionless area of pore pressure, normal function area, fracturing function area, and quasi-soil function area. The effective stress law of coal mass introduced by this paper is a constitutive equation in the study of coupled solid and fluid. This has significance in the drainage and outburst of methane in coal seam. 相似文献
98.
99.
本文提出了考虑炮口激波结构中的正激波强度、化学动力学和湍流射流混合的预测炮口二次燃烧点火的模型,得到了与实验相一致的结果。 相似文献
100.
Fei Liu Fei Wei Yu Zheng Yong Jin 《中国颗粒学报》2006,4(3):160-166
A mathematical model has been developed for the simulation of gas-particle flow and fluid catalytic cracking in downer reactors. The model takes into account both cracking reaction and flow behavior through a four-lump reaction kinetics coupled with two-phase turbulent flow. The prediction results show that the relatively large change of gas velocity affects directly the axial distribution of solids velocity and void fraction, which significantly interact with the chemical reaction. Furthermore, model simulations are carried out to determine the effects of such parameters on product yields, as bed diameter, reaction temperature and the ratio of catalyst to oil, which are helpful for optimizing the yields of desired products. The model equations are coded and solved on CFX4.4. 相似文献